Hi
Although I have never tried to combine end of roll filaments, I have made O-rings out of ninjaflex material.
What I’ve done is to take two pieces of wood.
used a utility knife blade as a spacer and glued the wood together.
Then
I drilled a hole through both pieces of wood at the exact same size as the ninjaflex material 3mm filament diameter.
I pushed the ninjaflex into the wood pieces and heated the utility knife blade until it was glowing red.
Then
I inserted the utility knife blade into the slot of my wood block assembly and pressed the ninjaflex material together.
When I could feel the ninjaflex start to melt, I pulled the utility knife blade out and pressed the ninjaflex together as far as I could go.
After the ninjaflex cooled down, I broke the wood pieces and removed the newly created O-Ring.
Now I will say that my ninjaflex o-ring project was a one time experiament.
When the wood was removed, there was a lump of material larger than the diameter of my filament and some wood char contamination, BUT
I put the o-ring in the freezer for a day.
When I pulled it out, I cut most of the large diameter flange with a razor knife and sanded the rest smooth.
Ninjaflex is almost impossible to trim without freezing it.
The end result was a good usable o-ring.
While I did not test it to destruction, I will be doing that again in the future.
…
I hope my little experiment will help you in your endevour.
Just my 2 cents worth.